Fe-Th (Iron-Thorium)

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چکیده

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Thorium divanadate dihydrate, Th(V2O7)(H2O)2

The title compound, Th(V(2)O(7))(H(2)O)(2), was synthesized by a hydro-thermal reaction. The crystal structure consists of ThO(7)(OH(2))(2) tricapped trigonal prisms that share edges, forming [ThO(5)(OH(2))(2)](n) chains along [010]. The edge-sharing ThO(7)(OH(2))(2) polyhedra share one edge and five vertices with the V(2)O(7) divanadate anions having a nearly ecliptic conformation parallel to ...

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Thorium and Iron Content of Mine Dusts

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Properties of the Only Thorium Fullerene, Th@C84, Uncovered.

Only a single thorium fullerene, Th@C84, has been reported to date (Akiyama, K.; et al. J. Nucl. Radiochem. Sci. 2002, 3, 151-154). Although the system was characterized by UV-vis and XANES (X-ray absorption near edge structure) spectra, its structure and properties remain unknown. In this work we used the density functional calculations to identify molecular and electronic structure of the Th@...

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Role of Iron (Fe) in Body

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The Th=C double bond: an experimental and computational study of thorium poly-carbene complexes.

The first thorium poly-carbene complexes [(Ph(2)P=S)(2)C](2)Th(DME) (2) and [{[(Ph(2)P=S)(2)C](3)Th}Li(2)(DME)](n) (3) have been prepared and structurally characterized. DFT calculations reveal that the Th=C bond is polarized toward the nucleophilic carbene carbon atom, which is further verified by the experimental observation that the Th=C bond shows a nucleophilic behavior with Ph(2)CO.

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ژورنال

عنوان ژورنال: Journal of Phase Equilibria and Diffusion

سال: 2011

ISSN: 1547-7037,1863-7345

DOI: 10.1007/s11669-011-9966-y